Product ID:6903, ACETIC ACID GLACIAL
MSDS Date:04/19/1990
FSC:6810
NIIN:00N030151
MSDS Number: BPDRV

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865-2219
US

Emergency Phone: 908-859-2151;800-424-9300(CHEMTREC)

Info Phone: 800-582-2537

Cage: DO803

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

ACETIC ACID (SARA III); (ACETIC ACID, GLACIAL)

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 90-100%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM; 15 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WITH WATER. DO NOT ALLOW TO ENTER DRAIN OR SEWER

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL RAT) 3310 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:RESP SYS, EYES, SKIN,
TEETH & LUNGS. ACUTE:INHAL:SEV IRRIT/BURNS OF RESP SYS, PULM EDEMA,
LUNG INFLAMM, HDCH, COUGHING, DFCLT BRTHG, DIZZ, CHEST PAINS, TEETH
DAM & RESP FAILURE. SKIN:SEV BURNS. MAY CAUSE DERM. EYE:SEV BURNS
&PERM EYE DAMAGE. INGEST: BURNS TO MOUTH & THROAT, NAUS, VOM, (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:GASTROINTESTINAL IRRITATION, DIARRHEA,
SHOCK & MAY BE FATAL. CHRONIC:LUNG DAMAGE & TEETH DAMAGE.
Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE & SKIN
DISORDERS.

First Aid:INGEST:CALL MD. DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE
WATER, MILK OR MILK OF MAGNESIA. INHAL:REMOVE TO FRESH AIR. IF NOT
BRTHG, GIVE ARTF RESP. IF BRTHG IS DIFFICULT, GIVE OXYGEN. SKIN:
IMMED FLU SH W/PLENTY OF WATER FOR AT LEAST 15 MINS WHILE REMOVING
CONTAMD CLTHG & SHOES. WASH CLTHG BEFORE REUSE. EYES:IMMED FLUSH
W/PLENTY OF WATER FOR AT LEAST 15 MINS.

Flash Point Method:CC
Flash Point:103F,39C
Lower Limits:19.9%
Upper Limits:4.0%
Extinguishing Media:USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL OR
CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE CLOTHING . MOVE CONTRS FROM FIRE AREA IF IT CAN BE DONE
W/ OUT RISK. USE WATER TO KEEP FIRE (SUPP DATA)
Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURF TO DISTANT IGNIT
SOURCES & FLASH BACK. CLSD CONTRS EXPOSED TO HEAT MAY EXPLODE. CONT
W/ STRONG OXIDIZERS MAY CAUSE FIRE. (SUPP DATA)

Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
SHUT OFF IGNIT SOURCES; NO FLARES/SMKNG/FLAMES IN AREA. STOP LEAK
IF YOU CAN W/OUT RISK. NEUT SPILL W/SODA ASH/LIME. W/CLEAN SHOVEL,
CAREFULLY PLACE MATL INTO CLEAN, DRY CONTR & COVER. REMOVE (SUPP
DATA)
Neutralizing Agent:J T BAKER NEUTRASORB(R) OR TEAM(R) 'LOW NA+' ACID
NEUTS ARE RECOM FOR SPILLS.

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTD,
FLAMM LIQ STOR AREA/CABINET ABOVE 17C. KEEP CONTR TIGHTLY CLSD.
KEEP AWAY FROM HEAT/ SPARKS/FLAME. USE W/ADEQ VENT.
Other Precautions:DANGER. COMBUSTIBLE. CAUSES SEVERE BURNS. HARMFUL IF
SWALLOWED OR INHALED. DO NOT GET IN EYES, ON SKIN OR ON CLTHG.
AVOID BREATHING VAPOR. KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:RESPIRATORY PROT REQUIRED IF AIRBORNE
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 500 PPM, A
NIOSH/MSHA APPRVD CHEMICAL CARTRIDGE RESPIRATOR W/ACID/ORGANIC
CARTRIDGE IS RECOM. ABOVE THIS LEVEL, A NIOSH/MSHA APPRVD SCBA IS
ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:NEOPRENE GLOVES RECOMMENDED.
Eye Protection:CHEM WORK GOGGS/FULL LENGTH FSHLD
Other Protective Equipment:UNIFORM, PROTECTIVE SUIT, LAB COAT, APRON,
VENT HOOD & CLASS B EXTINGUISHER. EMERGENCY EYEWASH & DELUGE SHOWER
.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH:2.4 (1.0M SOLUTION). FIRE FIGHT PROC: EXPOSED CONTRS COOL. EXPLO
HAZ:REACTS W/MOST METALS TO PRDCE HYDROGEN GAS, WHICH CAN FORM AN
EXPLOS MIX W/AIR. MATLS TO AVOID:PEROXIDE, ALKALIES, CARBONATES, S
TRONG BASES, AMINES, PHOSPHORUS TRICHLORIDE & PHOSPHORUS
PENTACHLORIDE. SPILL PROC:FROM SPILL AREA. FLUSH AREA (ING 2)

HCC:F6
Boiling Pt:B.P. Text:244F,118C
Melt/Freeze Pt:M.P/F.P Text:62.0F,16.7C
Vapor Pres:11 @ 20C
Vapor Density:2.1
Spec Gravity:1.05 (H2O=1)
pH:SUPDAT
Evaporation Rate & Reference:0.97 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE (100%)
Appearance and Odor:COLORLESS LIQUID; VINEGAR LIKE ODOR.
Percent Volatiles by Volume:100

STRONG OXIDIZING AGENTS, MOST COMMON METALS (EXCEPT ALUM), CHROMIC,
NITRIC & SULFURIC ACIDS, HYDROGEN (SUPP DATA)
Stability Condition to Avoid:HEAT, FLAMES & OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CO & CO2.

Waste Disposal Methods:DISPOSE IN ACCORDANCE W/ALL APPLICABLE FEDERAL,
STATE & LOCAL ENVIRONMENTAL REGULATIONS.

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